Electron attachment to nitro compounds in liquid cyclohexane

Electron attachment to the interhalogen compounds ClF, ICl, and IBr

Dissociative electron attachment to DNA.

Electron-stimulated desorption of anions from thin films of linear and supercoiled DNA is investigated in the range 3-20 eV. Resonant structures are observed with maxima at 9.4+/-0.3, 9.2+/-0.3, and 9.2+/-0.3 eV, respectively, in the yield dependence of H-, O-, and OH- on the incident electron energy. Their formation is attributed to dissociative electron attachment.

Effect of an Electric Field on Electron Attachment to SF6 in Liquid Ethane and Propane

The effect of an external electric field, E, on the electron attachment rate constant, ke, of SFg was studied by a pulsed-conductivity technique in liquid ethane and propane at temperatures ranging from 133—176 K and 156—216 K, respectively. At constant temperature, ke was independent of E at fields less than Ec, the critical field above which the mobility becomes fielddependent, but at E> Ec, ...

Directionality of π-holes in nitro compounds.

A statistical survey of the Cambridge Structural Database reveals that the interaction between the π-holes of nitro groups and electron-rich atoms is somewhat directional. High-level ab initio computations indicate energies up to -6.6 kcal mol(-1).

Infrared Studies of Rotational and Vibrational Relaxation in Liquid Cyclohexane

The above relationship implies that vibrational and rotational relaxation are statistically independent. When a Raman investigation of the isotropic scattering of the same band is possible (in the case of vibrations which belong to the totally symmetric species), 0Vib (t) is often taken from the FT of the isotropic Raman scattering and CTOt(t) may be calculated [2]. However, for molecules with ...